Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 20, Pages 3947-3950Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc09527a
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Funding
- Chevreul Institute [FR 2638]
- Ministere de l'Enseignement Superieur et de la Recherche, Region Nord - Pas de Calais
- FEDER
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This study demonstrates the ability of ammonium uranyl peroxide nanoclusters U32R-NH4 to undergo exchange in between NH4+ and trivalent (Nd3+) or tetravalent (Th4+) cations in the solid state. It paves the way for new promising routes for the synthesis of mixed uranyl peroxides. The exchange ability may also be considered for solution decontamination and synthesis of new mixed actinideoxide precursors. Both of these applications could be used in the nuclear industry.
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