4.7 Article

A high performance hybrid battery based on aluminum anode and LiFePO4 cathode

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 8, Pages 1713-1716

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc09019a

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Funding

  1. U.S. Department of Energy's Office of Science, Basic Energy Science, Materials Sciences and Engineering Division

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A novel hybrid battery utilizing an aluminum anode, a LiFePO4 cathode and an acidic ionic liquid electrolyte based on 1-ethyl-3-methylimidazolium chloride (EMImCl) and aluminum trichloride (AlCl3) (EMImCl-AlCl3, 1-1.1 in molar ratio) with or without LiAlCl4 is proposed. The hybrid ion battery delivers an initial high capacity of 160 mA h g(-1) at a current rate of C/5. It also shows good rate capability and cycling performance.

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