4.7 Article

Ullmann coupling reaction of aryl chlorides on Au(111) using dosed Cu as a catalyst and the programmed growth of 2D covalent organic frameworks

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 56, Pages 8726-8729

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc03137d

Keywords

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Funding

  1. NSFC/China [21421004, 21190033, 21561162003, 21372072]
  2. Eastern Scholar Distinguished Professor Program
  3. Programme of Introducing Talents of Discipline to Universities [B16017]
  4. NCET [NCET-13-0798]
  5. Basic Research Program of the Shanghai Committee of Science and Technology [13M1400802]
  6. Fundamental Research Funds for the Central Universities

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The efficiency of Ullmann reaction of aryl chlorides on an Au(111) surface has been substantially increased by using dosed Cu as a catalyst. The different reactivity of aryl bromides and aryl chlorides has been exploited to design a programmed, on-surface synthesis to form 2D covalent organic frameworks.

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