Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 52, Pages 8152-8155Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc03414d
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Funding
- Board of Research in Nuclear Science (BRNS), Mumbai [37(2)/14/12/2015/BRNS/10549]
- Council of Scientific and Industrial Research (CSIR), New Delhi [CSC0108, CSC0130]
- CSIR
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The gold-catalyzed aminoalkynylation of alkynes for the synthesis of quinalizinones is reported. For instance, the reaction of pyridinoalkynes with 1-[(triisopropylsilyl)-ethynyl]-1,2-benziodoxol-3(1H)-one (TIPS-EBX) in the presence of a catalytic amount of AuCl at 50 8C afforded alkynylated quinalizinones in 57-87% yields.
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