Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 88, Pages 12948-12951Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc07199f
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Funding
- JSPS KAKENHI [JP16H04105, JP16H01002]
- Shorai Foundation for Science and Technology
- Deutsche Forschungsgemeinschaft
- Grants-in-Aid for Scientific Research [16H01002, 16H04105] Funding Source: KAKEN
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Selective synthesis of benzo[f] tetraphenes or benzo[g] chrysenes was achieved via aromatic C-F bond cleavage and unprecedented regioselective C-C bond formation depending upon the choice of aluminium reagents. On treatment with AlCl3, 2-(biphenyl-2-yl)-1fluoronaphthalenes afforded exclusively benzo[f] tetraphenes via C-C bond formation on the carbon atom gamma to the original position of the fluorine substituent. In contrast, alpha-selective C-C bond formation was promoted by treatment with gamma-Al2O3 to give benzo[g] chrysenes.
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