Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 39, Pages 6589-6592Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc02047j
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- CSIR
- CSIR-SPLENDID [BSC 0104]
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A general method for isoxazoles from readily available ynones using trimethylsilyl azide as an amino surrogate, likely via an unprecedented hydroazidation of the alkyne and denitrogenative cyclization, is demonstrated. The method neither required any catalyst nor demanded unusual conditions to afford the products with outstanding functional group compatibility.
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