Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 14, Pages 2972-2975Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc09857b
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Funding
- Argonne-Northwestern Solar Energy Research (ANSER) Center, an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [SC0001059]
- TomKat Charitable Trust
- National Science Foundation Graduate Research Fellowship [DGE-1122492]
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Hydroxamate binding modes and protonation states have yet to be conclusively determined. Molecular titanium(IV) phenylhydroxamate complexes were synthesized as structural and spectroscopic models, and compared to functionalized TiO2 nanoparticles. In a combined experimental-theoretical study, we find that the predominant binding form is monodeprotonated, with evidence for the chelate mode.
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