Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 2, Pages 362-365Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc06712j
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Funding
- Czech Science Foundation [P106/12/1276, 15-08992S]
- grant for long-term conceptual development of the Institute of Microbiology [RVO: 61388971]
- National Program of Sustainability [NPU I (LO-2015) MSMT - 34870/2013]
- Operational Program Prague - Competitiveness [CZ.2.16/3.1.00/22197, CZ.2.16/3.1.00/24501, CZ.2.16/3.1.00/24023]
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A method for enantioselective hydrogenation of cyclic imines with gaseous hydrogen has been developed. Easily accessible Noyori-Ikariya Ru(II) and Rh(III) complexes can be used directly without an inert atmosphere. Substrate activation has been achieved by trifluoroacetic acid. A new hydroxyl-functionalized complex is reported, showing high activity in transfer hydrogenation.
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