Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 82, Pages 12195-12198Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc06914b
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Funding
- NSERC of Canada
- Canada Research Chair
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A catalytic methodology for the conversion of amides to amines is reported. Of the 25 examples described, 14 examples involve the reduction of N-trifluoroacetamides to the corresponding trifluoroethylamines. These reductions are achieved by catalytic hydrosilylation of the amide mediated by an electrophilic phosphonium cation (EPC) catalyst.
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