Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 6, Pages 1230-1233Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc08519e
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Funding
- Polish National Science Centre [UMO-2013/09/N/ST8/02059]
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A new method for the asymmetric chemo-enzymatic Baeyer-Villiger oxidation of prochiral 4-methylcyclohexanone to (R)-4-methylcaprolactone in the presence of (+/-)-4-methyloctanoic acid, Candida Antarctica lipase B and 30% aq. H2O2 has been developed. A mechanism for the asymmetric induction based on kinetic resolution of racemic carboxylic acids is proposed.
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