Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 28, Pages 5037-5040Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc01494a
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Funding
- DOE grant [DE-FG02-98ER14888]
- US Dept. of Education
- U.S. Department of Energy (DOE) [DE-FG02-98ER14888] Funding Source: U.S. Department of Energy (DOE)
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A G(4)-quartet based hydrogel formed by self-assembly of borate esters of 5'-deoxy-5'-iodoguanosine (5'-IG 2) undergoes in situ cyclization to give 5'-deoxy-N3,5'-cycloguanosine (5'-cG 3). Formation of 5'-cG 3 causes self-destruction of the gel. This intramolecular cyclization can be used to release nucleoside analogs that have been pre-incorporated into the gel network.
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