Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 19, Pages 3797-3800Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc10076c
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Funding
- National Natural Science Foundation of China [51432006, 50925207, 51172100]
- Ministry of Science and Technology of China [2011DFG52970]
- Ministry of Education of China for the Changjiang Innovation Research Team [IRT14R23]
- 100 Talents Program of CAS
- Jiangsu Innovation Research Team
- Australian Research Council
- Ministry of Education and the State Administration of Foreign Experts Affairs for the 111 Project [B13025]
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An ammonium-crown ether host-guest supramolecular cation-templated synthetic methodology has been developed to construct a structurally unprecedented heterobicluster-metal coordination polymer (HCM-CP 1) based on tetranuclear clusters [WS4Cu3](+) with different connection environments, pentanuclear clusters [WS4Cu4](2+), and Cu+ building metal ions. HCM-CP 1 exhibits enhanced NLO properties, which may be ascribed to the incorporation of diverse building cluster components.
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