Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 40, Pages 6658-6661Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc02040b
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Funding
- Welch Foundation [AA 1846]
- Baylor University
- NSF-REU Program [CHE-1359231]
- Division Of Chemistry [1359231] Funding Source: National Science Foundation
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The synthesis of 1,2-oxaborines is accomplished via the reaction of pentaarylboroles with N-methylmorpholine-N-oxide via a 1,1-insertion reaction. The aromatic nature of 1,2-oxaborines was evaluated by computing nuclear independent chemical shift (NICS) values. Collectively, the experimental and computational studies indicate the unsaturated central BOC4 ring has appreciable aromatic character.
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