4.7 Article

A highly active and stable palladium catalyst on a g-C3N4 support for direct formic acid synthesis under neutral conditions

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 99, Pages 14302-14305

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc07401d

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Funding

  1. Basic Science Grant Climate Change Response project [NRF-2015R1A2A1A10054346, 2015M1A2A2074663]
  2. Korea Center for Artificial Photosynthesis (KCAP) [2009-0093880]
  3. MOTIE of Republic of Korea [10050509]

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Graphitic carbon nitride (g-C3N4) is applied as a support of the Pd catalyst for direct HCOOH synthesis by CO2 hydrogenation under neutral conditions. The high CO2 affinity of g-C3N4 is responsible for the enhanced catalytic activity and stability relative to the inert support such as a carbon nanotube.

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