Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 13, Pages 2705-2708Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc08682e
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Funding
- National Science Foundation [CHE-1301131]
- National Institutes of Health [VT-IMSD-GM072767]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1301131] Funding Source: National Science Foundation
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Appending anthracene units to [(bpy)(2)Ru(dpp)](2+) results in Ru(II) agents that exhibit dynamic photoreactivity towards DNA and protein. [(Anthbpy)(bpy)Ru(dpp)](2+) and [(Anthbpy)(2)Ru(dpp)](2+) are the first metal-organic Ru(II) agent with dpp ligands shown to photomodify DNA in the presence or absence of oxygen, while also binding protein in an oxygen-dependent manner.
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