Journal
JOURNAL OF LUMINESCENCE
Volume 221, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.jlumin.2020.117079
Keywords
2D hybrid organic-inorganic perovskite; Single crystals; Strong light-matter coupling; Photoluminescence; Low dimensional materials
Categories
Funding
- ERC [780757]
- FISR - C.N.R. Tecnopolo di nanotecnologia e fotonica per la medicina di precisione - CUP [B83B17000010001]
- project PERSEO-PERrovskite-based Solar cells: towards high Efficiency and long-term stability (Bando PRIN 2015 Italian Ministry of University and Scientific Research (MIUR)) [2488, 20155LECAJ]
- European Research Council (ERC) [780757] Funding Source: European Research Council (ERC)
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Hybrid organic-inorganic perovskites have emerged among the most promising materials for optoelectronic applications thanks to the great synthetic versatility that allows tailoring their structural and photophysical properties. In the two-dimensional (2D) crystalline form, these semiconductors have multiple-quantum-well structure with stable excitonic resonances at room temperature. In this work we present an easy and effective anti-solvent crystallization method to synthesize n = 1 and n = 2 dodecylammonium (DA) lead iodide perovskite single crystals. Different synthetic conditions have been explored and general guidelines for single crystals preparation are provided revealing that gamma-butyrolactone is the best solvent for its ability to weakly coordinate Pb2+ centers and that diethyl ether is the best anti-solvent because fast diffuses into the precursors solution. We exploit the high optical quality of the synthesized perovskites to observe strong exciton-photon coupling in single-crystal waveguides, avoiding the need to embed them within mirror microcavities.
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