Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 8, Pages 1717-1720Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc09673a
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- U.S. Air Force Asian Office of Aerospace Research and Development [FA2386-14-1-4043]
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An extremely bulky boryl-amide ligand, [N(SiMe3){B(DAB)}](-) (TBoN; DAB = (DipNCH)(2), Dip = C6H3Pr2i-2,6), has been utilised in the preparation of the first isolable, two-coordinate acyclic diaminosilylene (ADASi), viz. :Si(TBoN)(2). This is shown to have a frontier orbital energy separation, and presumed level of reactivity, intermediate between those of the two classes of previously reported isolable two-coordinate, acyclic silylenes.
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