4.7 Article

Uniform Li2S precipitation on N,O-codoped porous hollow carbon fibers for high-energy-density lithium-sulfur batteries with superior stability

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 73, Pages 10964-10967

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc06340c

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Funding

  1. U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering [DE-SC0005397]

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A lithium-polysulfide cell with superior stability is reported with N,O-codoped carbon hollow fiber (NCHF) sheets as a current collector. Due to the highly effective chemisorption and physical adsorption of lithium polysulfides on doped NCHF and a uniform Li2S precipitation during cycling, the Li2S6-impregnated NCHF electrodes exhibit high sulfur utilization and superior cycling stability even with a high areal sulfur loading of 6.2 mg cm(-2).

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