Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 72, Pages 10830-10833Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc05360b
Keywords
-
Categories
Funding
- NSERC of Canada
- Canada Research Chair
- DFG [IRTG 2027]
- Alexander von Humboldt Foundation
Ask authors/readers for more resources
Terminal and internal alkynes are efficiently hydroborated to (E)-alkenyl pinacol boronic esters with excellent yields and selectivities using a Lewis acid catalyst. In the case of Piers' borane (HB(C6F5)(2)) the borane acts as a pre-catalyst generating dissymmetrically gem-diborylated species of the form RCH2CR'(Bpin)(B(C6F5)(2)) which are the active catalysts.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available