Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 63, Pages 9773-9776Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc04482d
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Funding
- National Natural Science Foundation of China [21274165]
- Distinguished Professor Research Fund
- Fundamental Research Funds for the Central Universities from Central South University [2013zzts014]
- National Science Foundation [CHE-1506722, DMR-1205670, CHE-1151991]
- Research Corporation for Science Advancement [23224]
- Direct For Mathematical & Physical Scien [1151991] Funding Source: National Science Foundation
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A Ru2+-connected, metallo-organic ligand (L) with three free terpyridines was designed and synthesized. L was assembled with Zn2+ to generate a helical structure; however, when mixing L with a 1,2,3-tristerpyridine ligand (T), a thermodynamically stable 2D rhombus was assembled. Furthermore, this 2D rhomboidal structure can also be achieved through the dynamic transformation of pre-assembled helix H with T and Zn2+ at room temperature.
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