Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 65, Pages 10040-10043Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc04239b
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- MESR
- French Agence Nationale de la Recherche [ANR-10-LABX-57]
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The synthesis of biaryl compounds from aryldiazonium salts and arylboronic acids was achieved using PPh3AuCl as catalyst, CsF as base and acetonitrile as solvent. Combined to photosensitizers, irradiation by blue LEDs allowed accelerating the reaction and expanding its scope. Various functional groups were compatible including bromoaryls, iodoaryls, aldehydes and alcohols. A 2-iodobenzyl alcohol moiety was smoothly introduced by this method, enabling its consecutive isotopic labelling by a Pd-catalysed alkoxycarbonylation.
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