Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 45, Pages 7295-7298Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc03105f
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Funding
- CONACyT [153523, 21516, 574767]
- DGAPA [IA201615]
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Arenediazonium salts generated in situ fromanilines have been found for the first time to efficiently oxidize [AuCl(L)] (L = SMe2, PPh3) complexes in DMSO as a solvent, under thermal conditions. The structure of the [AuArCl2(L)] complexes formed has been confirmed by X ray diffraction analyses. These complexes have been used as intermediates, in a one pot cross-coupling reaction of anilines with silver acetylides.
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