Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 94, Pages 13668-13670Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc08178a
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Funding
- Nature Science Foundation of Jiangsu Province [BK 20131346, BK 20140776]
- National Natural Science Foundation of China [21476116, 21402093]
- Chinese Postdoctoral Science Foundation [2015M571761]
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Fluorine-containing organic compounds are gaining increasing importance in medicinal chemistry. Described herein is a mild and efficient method for the radical addition of olefins with TMSCF3 and TMSCF2R (R = COOEt or CF3) to deliver various alpha-trifluoromethylated ketones and alpha-fluoroolefinated ketones.
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