Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 52, Pages 8164-8167Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc02813f
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Funding
- DAAD (German Academic Exchange Service)
- Ministry of Education and Science of the Russian Federation
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Bulk binary ZrO2-based oxides efficiently catalyse non-oxidative dehydrogenation of isobutane to isobutylene. Their activity strongly depends on the kind of second metal oxide. So designed CrZrOx showed superior activity to industrially relevant catalysts with supported Pt or CrOx species. It was also stable under alternating dehydrogenation and oxidative regeneration cycles over ca. 110 h under different reaction conditions between 550 and 600 degrees C.
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