Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 69, Pages 10563-10565Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc06096j
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Funding
- DOE [DE-FG02-13ER16370]
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Contrary to recent reports, the dehydrocoupling of pinacol borane and 9-borabicyclononane with a variety of amines, alcohols and thiols can be achieved under mild conditions without catalyst. This process involves the formation of Lewis acid-base adducts featuring a hydridic B-H in close proximity to an acidic Nu-H.
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