Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 30, Pages 5234-5237Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc00857g
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Funding
- Ministry of Education, Singapore [R-279-000-409-112]
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An abnormal optical absorption at about 780 and 980 nm was observed for Au-25 nanoclusters (NCs) protected by negatively charged thiolate ligands collocating with positively or neutrally charged thiolate ligands, largely due to the resultant surface charge anisotropy on the NC surface which could induce structural distortions of the thiolated Au-25 NCs.
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