Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 100, Pages 14478-14481Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc08099e
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Funding
- Swedish Research Council
- K & A Wallenberg Foundation
- Swedish Energy Agency
- Department of Chemistry at KTH
- National Natural Science Foundation of China [21120102036, 91233201]
- National Basic Research Program of China (973 program) [2014CB239402]
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Iron porphyrins Fe-pE, Fe-mE, and Fe-oE were synthesized and their electrochemical behavior for CO2 reduction to CO has been investigated. The controlled potential electrolysis of Fe-mE gave exclusive 65% Faradaic efficiency (FE) whereas Fe-oE achieved quasi-quantitative 98% FE (2% H-2) for CO production.
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