Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 79, Pages 11811-11814Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc06370e
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Funding
- ERC Starting Grant [205442]
- MINECO [BIO2014-59131-R]
- Midwestern University
- DOE OBER
- NIH
- [GM-65440]
- European Research Council (ERC) [205442] Funding Source: European Research Council (ERC)
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Mo and Fe K-edge EXAFS analysis of NifQ shows the presence of a [MoFe3S4] cluster and a second independent Mo environment that includes Mo-O bonds and Mo-S bonds. Both environments are relevant to FeMo-co biosynthesis and may represent different stages of Mo biochemical transformations catalyzed by NifQ.
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