Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 98, Pages 14149-14152Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc08151g
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- Conacyt [128411, 128419, 245146]
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A main chain poly(crown ether) macromolecule has been crosslinked with a two binding site guest to afford a stimuli-responsive supramolecular polymeric network with pseudo-rotaxane nodes. This network forms gels and films that are responsive to temperature and solvent polarity; however, the materials can be shielded against both effects by transforming the pseudo-rotaxane junctions into rotaxane links, creating a mechanically locked structure.
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