Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 93, Pages 13600-13603Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc07962h
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Funding
- National Natural Science Foundation of China [21334002, 51573055, 51473052, 51373054, 51521002]
- National Basic Research Program of China (973 Program) [2013CB834705, 2014CB643504]
- Fundamental Research Funds for the Central Universities
- Introduced Innovative R&D Team of Guangdong [201101C0105067115]
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A micro-porous network thin film of core-tetrachlorinated perylene bisimide (PBI) was deposited by electrochemical polymerization, which showed reversible n-doping/dedoping processes at rather low potentials, accompanied by color changes from an orange red (neutral) state to a transparent (radical anion) state and further to an aquamarine (dianion) state. The film possesses preferable coloration efficiency and cycling stability (410000 cycles).
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