Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 79, Pages 11783-11786Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc06059e
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Funding
- French National Research Agency through the Laboratory of Excellence on Bio-driven chemistry (ARCANE) [ANR-11-LABX-0003-01]
- Laboratory of Excellence in Research on Medication and Innovative Therapeutics [ANR-10-LABX-0033-LERMIT]
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A carbon nanotube-cobaloxime nanohybrid was prepared through supramolecular assembly of tailored polymerizable amphiphiles, leading to the coordination of cobalt on pyridine-coated nanotubes. This material was used as a catalyst for hydrogen evolution in fully aqueous media. This study provides a definitive asset regarding the stability of the pyridine-cobalt axial bond under H-2 evolution turnover conditions.
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