Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 59, Pages 9271-9274Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc04173f
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Funding
- Hong Kong University Grants Committee Area of Excellence Scheme [AoE/P-03-08]
- Shenzhen Science and Technology Research Grant [JCYJ20150601102053067]
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Mn(V) nitrido complex [Mn(N)(CN)(4)](2-) is an efficient catalyst for visible-light induced oxidation of alkenes and alcohols in water using [Ru(bpy)(3)](2+) as a photosensitizer and [Co(NH3)(5)Cl](2+) as a sacrificial oxidant. Alkenes are oxidized to epoxides and alcohols to carbonyl compounds.
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