Journal
JOURNAL OF HAZARDOUS MATERIALS
Volume 398, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.jhazmat.2020.122944
Keywords
Oxytetracycline; Photoelectrochemical aptasensor; Bi4VO8Cl/N-GQDs; Tomato
Categories
Funding
- National Natural Science Foundation of China [21375050, 21675066]
- Priority Academic Program Development of Jiangsu Higher Education Institutions [PAPD-2018-87]
- Special Foundation of China Postdoctoral [2019TQ0127]
- Foundation of Key Laboratory of Sensor Analysis of Tumor Marker, Ministry of Education, Qingdao University of Science and Technology [SATM201807]
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Sensitive detection of oxytetracycline (OTC) has attracted increasing attention worldwide due to the relationship between food safety and human health problems. In this work, a visible-light-driven photoelectrochemical (PEC) OTC aptasensor was constructed using Bi4VO8Cl/nitrogen-doped graphene quantum dots (Bi4VO8Cl/N-GQDs) nanohybrids as photoactive material and OTC aptamer as identification element. Owing to the well matched heterojunction of Bi4VO8Cl and nitrogen-doped graphene quantum dots (N-GQDs), the photogenerated electron hole pairs could be separated effectively, so that the photocurrent intensity of as-prepared Bi4VO8Cl/N-GQDs nanohybrids was about 7 times higher than pure Bi4VO8Cl and had higher stability. The constructed signal-off PEC aptasensor realized OTC detection in tomato samples with excellent sensitivity, specificity and repeatability. The photocurrent decreased with the increase of OTC concentration in a range from 0.1 nM to 150 nM, and the detection limit was 0.03 nM (S/N = 3). The national standard method was used to compare with our method and the results were consistent.
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