4.7 Article

Diverse tetrahedral tetrazolate frameworks with N-rich surface

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 32, Pages 5625-5628

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc00589f

Keywords

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Funding

  1. 973 program [2012CB821705]
  2. NSFC [21425102, 21573236, 21521061]

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Three tetrahedral tetrazolate frameworks (TTFs) with SOD, srs and ctn topologies (TTF-4, -5 and -6) are obtained by using the anion and solvent as structure-directing agents. The resulting SOD-type TTF-4 shows high chemical stability as well as high CO2 uptake capacity.

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