4.7 Article

Controlling embedment and surface chemistry of nanoclusters in metal-organic frameworks

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 29, Pages 5175-5178

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc00659k

Keywords

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Funding

  1. European Commission through the European Research Council [ERC StG C3ENV GA 256962]
  2. University, State and Commonwealth Governments
  3. Australia China Science and Research Fund - Joint Research Centre for Energy [ACSRF00681]
  4. Australian Research Council LIEF grant [LE120100026]
  5. EPSRC [EP/N00938X/1]
  6. NIMS microstructural characterisation platform as a programme of Nanotechnology Platform'' of MEXT, Japan [A-15-AE-0017]
  7. Engineering and Physical Sciences Research Council [EP/N00938X/1] Funding Source: researchfish

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A combined theoretical and experimental approach demonstrates that nanocluster embedment into the pores of metal-organic frameworks (MOF) may be influenced by the chemical functionalisation of the MOF. Furthermore, this results in the surface functionalisation of the embedded nanoclusters, highlighting the potential of MOF scaffolds for the design and synthesis of novel functional materials.

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