4.7 Article

Tautomerization of 2,6-lutidines in the presence of B(C6F5)3 using catecholborane as a precatalyst

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 25, Pages 4655-4658

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc00347h

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Funding

  1. National Natural Science Foundation of China [21273042, 21372048, 21573044]

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2,6-Lutidine and its derivatives in the presence of B(C6F5)(3) undergo tautomerization to yield the corresponding enamine center dot B(C6F5)(3) adducts when catecholborane is applied as a precatalyst. This reaction provides a straightforward way for benzylic C-H borylation of lutidines.

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