Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 78, Pages 11681-11684Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc06675e
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- University of Catania
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A 3D supramolecular polymer based on calix[5]arene tethered poly(p-phenyleneethynylene) with a complementary porphyrin endowed with alkanediyldiammonium functions is prepared in solution but collapses when transferred to a chemically inert solid matrix forming a dispersion of de-phasing porphyrin aggregates. We found that a short thermal shock induces the de-aggregation of the porphyrin aggregates, and a partial restoration of the original 3D-supra-molecular architecture.
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