Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 17, Pages 3520-3523Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc10401g
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Funding
- ICIQ Foundation
- MINECO [CTQ2013-45938-P]
- AGAUR [2014 SGR 1059]
- European Research Council [ERC 278541 - ORGA-NAUT]
- Marie Curie COFUND action [2015-1-ICIQ-IPMP]
- Severo Ochoa Excellence Accreditation [SEV-2013-0319]
- ICREA Funding Source: Custom
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The conjugate addition of alpha-amino radicals to alkenylpyridines has been accomplished by the synergistic merger of Bronsted acid and visible light photoredox catalysis. Key to reaction development was the protonation of the alkenylpyridines that transiently generated a highly reactive, electrophilic pseudo-iminium ion intermediate. Initial investigations using chiral phosphoric acids provide clues on the feasibility of an enantioselective catalytic variant.
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