4.7 Article

Chirality induction using circularly polarized light into a branched oligofluorene derivative in the presence of an achiral aid molecule

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 9, Pages 1919-1922

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc08464d

Keywords

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Funding

  1. MEXT Project of Integrated Research on Chemical Synthesis
  2. Mitsubishi Foundation
  3. Royal Society
  4. EPSRC [EP/I029141]
  5. EPSRC [EP/I029141/1] Funding Source: UKRI
  6. Engineering and Physical Sciences Research Council [EP/I029141/1] Funding Source: researchfish

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Chirality induction into a uniform, star-shaped fluorene oligomer with a central truxene moiety (T3) was achieved using circularly polarized light in the presence of achiral fluorene or phenanthrene. Induction into T3 alone was difficult, suggesting that close chain packing realized through interactions of T3 with small molecules plays a role in chirality induction.

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