Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 9, Pages 1812-1815Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc08204h
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Funding
- Israel Science Foundation
- MINERVA foundation
- Kimmel Center for Molecular Design
- Swiss Friends of the Weizmann Institute of Science
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Hydrogenation of nitriles to primary amines constitutes an atom-efficient and environmentally benign synthetic reaction. Herein we present a novel complex based on earth-abundant iron, and its application in the catalytic homogeneous hydrogenation of (hetero)-aromatic, benzylic, and aliphatic nitriles to selectively form primary amines.
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