Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 9, Pages 1824-1826Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc08377j
Keywords
-
Categories
Funding
- NSF [CHE-1455348]
- U.S. Department of Education GAANN Award [P200A120170]
Ask authors/readers for more resources
A phosphine containing a 10-vertex carborane anion substituent and its subsequent ligation to a Rh(I) carbonyl complex is reported. The complex is characterized by NMR spectroscopy and a single crystal X-ray diffraction study. In addition, the inductive effects of both 10 and 12 vertex C-functionalized closo-carborane anions are elucidated via I.R. analysis of the CO stretching frequencies of two Rh carbonyl complexes. Unlike C-functionalized neutral o-carborane the 10 and 12-vertex carborane anions are both strong electron donor substituents.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available