Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 3, Pages 489-492Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc07390a
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Funding
- Chinese Academy of Sciences
- National Natural Science Foundation of China [21133011, 21373246, 21522309]
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A simple iron-catalyzed aerobic oxidative C-C sigma-bond cleavage of ketones has been developed. Readily available and environmentally benign air is used as the oxidant. This reaction avoids the use of noble metal catalysts or specialized oxidants, chemoselectively yielding carbon chain-shortened aldehydes, ketones and 1,2-dicarbonyl compounds without overoxidation.
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