Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 33, Pages 5746-5748Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc01759b
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Funding
- National Science Foundation [CHE-1565676, CHE-1361178]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1265212, 1565676] Funding Source: National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1361178] Funding Source: National Science Foundation
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Reaction of carbene-stabilized diphosphorus, L:P-P:L (5) (L: = : C{N(2,6-(Pr2C6H3)-C-i)CH}(2)) with pyridine hydrochloride yields [L:(H)P-P: L]Cl (6), a salt containing the HP2+ cation-the elusive phosphorus analogue of the well known diazonium cation, HN2+. In addition to reporting the synthesis and structure, the nature of (6) was further probed by DFT computations. Interestingly, carbenes may be employed to deprotonate (6), affording the starting material (5).
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