4.7 Article

Multifaceted chelating mu-(eta(3):eta(3)-antifacial)-(cis-C4R2H2) coordination motif in binuclear complexes

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 74, Pages 11056-11059

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc05535d

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Funding

  1. Research Grants Council of the Hong Kong SAR, China [CityU 11300414]

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A novel mu-C4R2H2 core structure (formed by an unprecedented regioselective, redox-neutral C(sp(2))-C(sp(2)) coupling process) in binuclear group 4 complexes displays adaptable coordination and accommodates different metal sizes, and is sufficiently robust to promote interesting catalytic reactivity at the bimetallic centers.

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