Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 35, Pages 5981-5984Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc01635a
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Funding
- University Grants Committee of Hong Kong Special Administrative Region, China [AoE/P-03/08]
- City University of Hong Kong [7004402]
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M8L12 cubic cages (M = Zn-II or Cd-II), with all eight metal ions having all facial A or facial A configurations and having an encapsulated anion, were prepared by the self -assembly of m-xylene-bridged imidazolyl-imine ligands and MX2 (X = PF6- SbF6- TfO-) salts; the encapsulated anion exchange with different anions (SbF6, Tf2N-, NO3-, TsO-) was studied and the results with NO3- and TsO- indicate that anions on the cage surfaces affect the encapsulated anion exchange and the occupancy of the cage.
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