Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 58, Pages 9125-9128Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc01135g
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Funding
- National Science Foundation of China [21472146]
- Department of Science and Technology of Shaanxi Province [2015KJXX-02]
- Ministry of Science and Technology of PRC (973 program for young scientists) [2014CB548200]
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An efficient transition-metal-free photochemical method featuring excellent functional group tolerance, mild reaction conditions and short reaction times has been discovered and developed for the synthesis of (hetero)aryl trimethylstannanes from (hetero)aryl halides. A photo-initiated radical chain mechanism was proposed based on preliminary mechanistic studies.
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