Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 45, Pages 7310-7313Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc03144g
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Funding
- National Natural Science Foundation of China [21271149, 21325102]
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Four heteroditopic macrocyclic ligands incorporating both anion coordination sites (tris-urea units) and a cation binding fragment (polyether) were designed for possible application in molecular devices. Sandwich-type phosphate complexes were formed, which display a reversible rotation around the anion upon protonation/deprotonation of phosphate and binding of the cation (Emim(+)).
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