4.7 Article

Covalent interlocking of glucose oxidase and peroxidase in the voids of paper: enzyme-polymer spider webs''

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 12, Pages 2593-2596

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc00037a

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Funding

  1. NSF EAGER award [DMR-1441879]
  2. UCONN VPR Research Excellence Award

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A modular, general method for trapping enzymes within the voids of paper, without chemical activation of cellulose, is reported. Glucose oxidase and peroxidase were crosslinked with poly(acrylic acid) via carbodiimide chemistry, producing 3-dimensional networks interlocked in cellulose fibers. Interlocking prevented enzyme activity loss and enhanced the washability and stability.

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