Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 19, Pages 3750-3753Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc10072k
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Funding
- CSIRO Julius Career Award
- Australian Research Council [DE40101359]
- Trinity Hall (University of Cambridge)
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The porosity of a glass formed by melt-quenching a metal-organic framework, has been characterized by positron annihilation lifetime spectroscopy. The results reveal porosity intermediate between the related open and dense crystalline frameworks ZIF-4 and ZIF-zni. A structural model for the glass was constructed using an amorphous polymerization algorithm, providing additional insight into the gas-inaccessible nature of porosity and the possible applications of hybrid glasses.
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