Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 71, Pages 10779-10782Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc05509e
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Funding
- Nature Science Foundation of Jiangsu Province [BK 20131346, BK 20140776]
- National Natural Science Foundation of China [21476116, 21402093]
- Chinese Postdoctoral Science Foundation [2015M571761, 2016T90465]
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An efficient and stereoselective synthesis of vinylsilanes via copper-catalyzed direct silylation of alkenes with silanes was developed. This study offers a new and expedient strategy for the synthesis of synthetically useful alkenyl organosilicon compounds in satisfactory yields and may provide a low-cost and environmentally benign alternative to currently employed precious metal systems for alkene silylation. Moreover, the transformation is proposed to proceed via a radical process and exhibits a broad substrate scope and good functional group tolerance.
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